A magnetically highly frustrated CuII27 coordination cluster containing a Cu18 folded-sheet motif-Reference-Cited by-同舟云学术

A magnetically highly frustrated CuII27 coordination cluster containing a Cu18 folded-sheet motif

Published:2015 Issue:13 Volume:51 Page:2702-2705
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kühne Irina A.¹²³⁴,Kostakis George E.⁵²⁶⁴^ORCID,Anson Christopher E.¹²³⁴,Powell Annie K.¹²³⁴⁵

Affiliation:

1. Institut für Anorganische Chemie

2. Karlsruhe Institute of Technology (KIT)

3. D-76131 Karlsruhe

4. Germany

5. Institut für Nanotechnologie

6. D-76021 Karlsruhe

Abstract

In this work we report the synthesis, a topological description and magnetic properties of a high-nuclearity homometallic Cu^II coordination cluster which contains a Cu₁₈ folded-sheet motif capped by an additional Cu₉ unit which can be viewed as a “chicken in a basket” motif.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C4CC09469G

Reference16 articles.

1. Inducing Single-Molecule Magnetism in a Family of Loop-of-Loops Aggregates: Heterometallic Mn40Na4 Clusters and the Homometallic Mn44 Analogue

2. A Co36Cluster Assembled from the Reaction of Cobalt Pivalate with 2,3-Dicarboxypyrazine

3. Redox Behavior of [H6-nNi38Pt6(CO)48]n- (n = 4−6) Anions: A Series of Metal Carbonyl Clusters Displaying Electron-Sink Features

4. Giant Single-Molecule Magnets: A{Mn84} Torus and Its Supramolecular Nanotubes

5. Structure and Magnetic Properties of a Giant Cu44II Aggregate Which Packs with a Zeotypic Superstructure

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