Site-selective unidirectional benzylic sp3 C–H oxidation of dodecahydrotriphenylene with RuCl3–NaIO4: formation of benzylic ketones-Reference-Cited by-同舟云学术

Site-selective unidirectional benzylic sp3 C–H oxidation of dodecahydrotriphenylene with RuCl3–NaIO4: formation of benzylic ketones

Published:2021 Issue:55 Volume:11 Page:34498-34502
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Bhatt Gaurang J.¹^ORCID,Deota Pradeep T.¹^ORCID,Upadhyay Deepak²,Jha Prafulla K.³^ORCID

Affiliation:

1. Applied Chemistry Department, Faculty of Technology & Engineering, The Maharaja Sayajirao University of Baroda, Vadodara-390 001, Gujarat, India

2. Department of Applied Physics, Faculty of Technology & Engineering, The Maharaja Sayajirao University of Baroda, Vadodara-390 001, Gujarat, India

3. Department of Physics, Faculty of Science, The Maharaja Sayajirao University of Baroda, Vadodara-390 001, Gujarat, India

Abstract

Dodecahydrotriphenylene, a higher homologue of trindane chemoselectively undergoes unidirectional benzylic sp3 C–H oxidation and the central benzene ring remains intact unlike that in trindane under similar reaction conditions.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RA/D1RA06897K

Reference42 articles.

1. Aryl−Aryl Bond Formation by Transition-Metal-Catalyzed Direct Arylation

2. C−C, C−O, C−N Bond Formation on sp2 Carbon by Pd(II)-Catalyzed Reactions Involving Oxidant Agents

3. Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

4. Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity

5. Functionalization of Organic Molecules by Transition-Metal-Catalyzed C(sp3)H Activation

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