Nitrogen-doped carbocatalyst activated persulfate (PS) for oxidation polymerization of bisphenol A (BPA): importance of nonradical activation of PS-Reference-Cited by-同舟云学术

Nitrogen-doped carbocatalyst activated persulfate (PS) for oxidation polymerization of bisphenol A (BPA): importance of nonradical activation of PS

Published:2023 Issue:19 Volume:25 Page:13716-13727
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Wang Caihong¹,Liu Yong¹²,Han Fengshen¹,Han Yongzhe¹,Liu Tianyu¹,Ren Haitao³,Han Xu⁴^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin, 300384, P. R. China

2. Tianjin Key Laboratory of Organic Solar Cells and Photochemical Conversion, Tianjin, 300384, P. R. China

3. School of Textile Science and Engineering, Tiangong University, Tianjin, 300387, P. R. China

4. School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300350, P. R. China

Abstract

Persulfate is activated on the N-doped carbocatalyst via the nonradical pathway under alkaline conditions, which then selectively oxidizes to BPA polymers via the H-abstraction pathway, and the oxidizing intermediate can be detected on carbocatalysts.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP00659J

Reference67 articles.

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4. Rate Constants for Reactions of Inorganic Radicals in Aqueous Solution

5. Advanced Oxidation Processes (AOPs) in Wastewater Treatment

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