Circular dichroism and circularly polarised luminescence of bipyrenyl oligopeptides, with piperidines added in the peptide chains

Author:

Mimura Yuki12345,Kitamura Sayaka12345,Shizuma Motohiro6785,Kitamatsu Mizuki12345,Imai Yoshitane12345ORCID

Affiliation:

1. Department of Applied Chemistry

2. Faculty of Science and Engineering

3. Kindai University

4. Osaka 577-8502

5. Japan

6. Department of Biochemistry

7. Osaka Research Institute of Industrial Science and Technology

8. Osaka 536-8553

Abstract

We found that chiral oligopeptides bearing two-pendant pyrenyl units exhibited circularly polarised luminescence (CPL) originating from intramolecular excimers in various solvents, and the sign of their CPL signals depended on the solvent and piperidine unit in peptide chain.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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