Visible-light-mediated aerobic Ritter-type C–H amination of diarylmethanes using DDQ/<i>tert</i>-butyl nitrite-Reference-Cited by-同舟云学术

Visible-light-mediated aerobic Ritter-type C–H amination of diarylmethanes using DDQ/tert-butyl nitrite

Published:2022 Issue:44 Volume:20 Page:8756-8760
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Li Tianci¹,Yang Jiangyu¹²,Yin Xin¹²,Shi Jinhua¹,Cao Qun³^ORCID,Hu Miaomiao¹,Xu Xiaowen¹,Li Meichao¹,Shen Zhenlu¹^ORCID

Affiliation:

1. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310014, China

2. Zhejiang Jitai New Materials Co., Ltd, Shaoxing 312369, China

3. School of Chemistry and Chemical Engineering, Queen's University Belfast, David Keir Building, Belfast, BT9 5AG, UK

Abstract

A metal-free photocatalytic Ritter-type C–H amination of diarylmethanes using O2 as an oxidant has been developed using a co-catalytic system of DDQ and TBN and offers a low cost, sustainable way to synthesise secondary amides under mild conditions.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D2OB01713J

Reference38 articles.

1. Transition Metal-Catalyzed C–H Amination: Scope, Mechanism, and Applications

2. Metal-Catalyzed Nitrogen-Atom Transfer Methods for the Oxidation of Aliphatic C–H Bonds

3. Oxidative C–H amination reactions