Radical copolymerisation of chlorotrifluoroethylene with isobutyl vinyl ether initiated by the persistent perfluoro-3-ethyl-2,4-dimethyl-3-pentyl radical

Author:

Puts Gerard1234,Lopez Gérald56789,Ono Taizo10111213,Crouse Philip1234,Ameduri Bruno56789

Affiliation:

1. Department of Chemical Engineering

2. University of Pretoria

3. Pretoria 0002

4. South Africa

5. Institut Charles Gerhardt

6. Ingénierie et Architectures Macromoléculaires

7. UMR CNRS 5253

8. Ecole Nationale Supérieure de Chimie de Montpellier

9. 34296 Montpellier

10. National Institute of Advanced Industrial Science and Technology

11. Research Institute of Instrumentation Frontier

12. Nagoya

13. Japan

Abstract

The radical copolymerisation of chlorotrifluoroethylene with isobutyl vinyl ether initiated by trifluoromethyl radicals generated by β-scission of a persistent radical is reported.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference37 articles.

1. J. G. Drobny , Technology of Fluoropolymers, CRC Press, Boca Raton, 2014

2. S. Ebnesajjad , Fluoroplastics, Volume 1: Non-Melt Processible Fluoroplastics, Elsevier Science, Amsterdam, 2000

3. S. Ebnesajjad , Fluoroplastics, Volume 2: Melt Processible Fluoroplastics: The Definitive User's Guide, Elsevier Science, Amsterdam, 2002

4. (Co)polymers of Chlorotrifluoroethylene: Synthesis, Properties, and Applications

5. B. Ameduri and B.Boutevin, Well-Architectured Fluoropolymers: Synthesis, Properties and Applications: Synthesis, Properties and Applications, Elsevier Science, 2004

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