Dissolution kinetics of a sodium borosilicate glass in Tris buffer solutions: impact of Tris concentration and acid (HCl/HNO3) identity

Author:

Stone-Weiss Nicholas1234ORCID,Smith Nicholas J.5674ORCID,Youngman Randall E.5674ORCID,Pierce Eric M.89104,Goel Ashutosh1234ORCID

Affiliation:

1. Department of Materials Science and Engineering

2. Rutgers, The State University of New Jersey

3. Piscataway

4. USA

5. Science and Technology Division

6. Corning Incorporated

7. Corning

8. Environmental Sciences Division

9. Oak Ridge National Laboratory

10. Oak Ridge

Abstract

Borosilicate glass dissolution behavior in Tris-based buffer solutions was observed to be unimpacted by the acid identity, have an optimal Tris concentration of ∼0.1 M, and form Tris–boron complexes with temperature-dependent stability.

Funder

Division of Materials Research

Office of Science

Nuclear Energy University Programs

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference75 articles.

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3. ASTM (American Society for Testing and Materials) Standard: C1220-17, ASTM International, West Conshohocken, PA, 2017

4. Experimental determination of the effect of the ratio of B/Al on glass dissolution along the nepheline (NaAlSiO4)–malinkoite (NaBSiO4) join

5. An experimental study of the dissolution rates of simulated aluminoborosilicate waste glasses as a function of pH and temperature under dilute conditions

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