Photoinduced electron transfer in supramolecular ruthenium–porphyrin assemblies
Author:
Affiliation:
1. Organic Semiconductor Centre
2. EaStCHEM School of Chemistry
3. University of St Andrews
4. St Andrews
5. UK
6. CEISAM UMR CNRS 6230
7. Université de Nantes
8. 44322 Nantes Cedex 3
9. France
10. Institut Universitaire de France
Abstract
We present dynamic supramolecular systems composed of a Ru(ii) complex of the form of [Ru(dtBubpy)2(qpy)][PF6]2 (where dtBubpy is 4,4′-di-tert-butyl-2,2′-dipyridyl and qpy is 4,4′:2′,2′′:4′′,4′′′-quaterpyridine) and zinc tetraphenylporphyrins (ZnTPP), through non-covalent interactions between the distal pyridines of the qpy and the zinc of ZnTPP.
Funder
European Research Council
Engineering and Physical Sciences Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C6DT04414J
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