In situ ligand exchange-mediated 0D/1D transformation of a polyoxovanadate-Reference-Cited by-同舟云学术

In situ ligand exchange-mediated 0D/1D transformation of a polyoxovanadate

Published:2017 Issue:5 Volume:46 Page:1618-1623
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Wendt M.¹²³⁴,Polzin P.¹²³⁴,van Leusen J.¹⁵⁶⁴,Näther C.¹²³⁴^ORCID,Kögerler P.¹⁵⁶⁴^ORCID,Bensch W.¹²³⁴^ORCID

Affiliation:

1. Institute of Inorganic Chemistry

2. Christian-Albrechts University of Kiel

3. 24118 Kiel

4. Germany

5. RWTH Aachen University

6. 52074 Aachen

Abstract

The antimonato-polyoxovanadate {Ni^II(en)₃}₃[VIV15SbIII6O₄₂(H₂O)]·ca.15H₂O was utilized as a synthon for the solvothermal in situ generation of the new compound {Ni^II(phen)₃}₂[{Ni^II(en)₂}VIV15SbIII6O₄₂(H₂O)]·19H₂O, a rearrangement induced by ligand metathesis.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C6DT04412C

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5. [ASVV12VV2IVO40]7⊖, a Topologically Interesting, Mixed Valence Cluster as Model for Vanadium Minerals Formed by Weathering

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