Covalency-aided electrochemical CO<sub>2</sub> reduction to CO on sulfide-derived Cu

Covalency-aided electrochemical CO₂ reduction to CO on sulfide-derived Cu–Sb

Published:2024 Issue:3 Volume:12 Page:1840-1851
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Goh Daniel Yong Yi¹²^ORCID,Yam Kah Meng³⁴,Rekhi Lavie³^ORCID,Handoko Albertus Denny⁵^ORCID,Tan Ying Chuan⁵^ORCID,Wang Yong¹^ORCID,Tan Joel Ming Rui¹⁶,Choksi Tej Salil³⁴^ORCID,Lum Yanwei²^ORCID,Wong Lydia Helena¹⁶^ORCID

Affiliation:

1. School of Materials Science and Engineering, Nanyang Technological University, 639798, Singapore

2. Institute of Materials Research and Engineering, Agency for Science, Technology and Research, 138635, Singapore

3. School of Chemistry, Chemical Engineering and Biotechnology, Nanyang Technological University, 637459, Singapore

4. Cambridge Centre for Advanced Research and Education in Singapore, 138602, Singapore

5. Institute of Sustainability for Chemicals, Energy and Environment, Agency for Science, Technology and Research, 138635, Singapore

6. Singapore-HUJ Alliance for Research and Enterprise (SHARE), Campus for Research Excellence and Technological Enterprise (CREATE), 138602, Singapore

Abstract

Sulfide-derived catalysts tend to be more selective to HCOO− with suppression of CO production. We found that sulfur-doped Cu–Sb breaks the trend with improved CO selectivity.

Funder

National Research Foundation Singapore

Ministry of Education – Singapore

Agency for Science, Technology and Research

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TA/D3TA04777F

Reference55 articles.

1. Direct and selective hydrogenation of CO2 to ethylene and propene by bifunctional catalysts

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