Stereodivergent entry to β-branched β-trifluoromethyl α-amino acid derivatives by sequential catalytic asymmetric reactions-Reference-Cited by-同舟云学术

Stereodivergent entry to β-branched β-trifluoromethyl α-amino acid derivatives by sequential catalytic asymmetric reactions

Published:2021 Issue:30 Volume:12 Page:10233-10241
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Corti Vasco¹²³⁴^ORCID,Riccioli Riccardo¹²³⁴,Martinelli Ada¹²³⁴,Sandri Sofia¹²³⁴,Fochi Mariafrancesca¹²³⁴^ORCID,Bernardi Luca¹²³⁴^ORCID

Affiliation:

1. Department of Industrial Chemistry “Toso Montanari” and INSTM RU Bologna

2. Alma Mater Studiorum – University of Bologna

3. 40136 Bologna

4. Italy

Abstract

A one-pot approach to β-branched β-trifluoromethyl α-amino acids, grounded on the reduction – ring opening of Erlenmeyer–Plöchl azlactones, and complementary to conventional catalytic asymmetric hydrogenation, is presented.

Funder

Università di Bologna

Ministero dell’Istruzione, dell’Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC01442K

Reference73 articles.

1. Stereocontrolled routes to β,β′-disubstituted α-amino acids

2. Ag-Catalyzed Diastereo- and Enantioselective Synthesis of β-Substituted Tryptophans from Sulfonylindoles

3. Highly diastereo- and enantioselective synthesis of syn-β-substituted tryptophans via asymmetric Michael addition of a chiral equivalent of nucleophilic glycine and sulfonylindoles

4. Asymmetric Catalytic 1,6-Conjugate Addition/Aromatization ofpara-Quinone Methides: Enantioselective Introduction of Functionalized Diarylmethine Stereogenic Centers

5. Syn-Selective Synthesis of β-Branched α-Amino Acids by Alkylation of Glycine-Derived Imines with Secondary Sulfonates

Cited by 15 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Applications of Hantzsch Esters in Organocatalytic Enantioselective Synthesis;Catalysts;2023-02-16

2. Stereodivergent Construction of 1,3‐Chiral Centers via Tandem Asymmetric Conjugate Addition and Allylic Substitution Reaction;Angewandte Chemie International Edition;2023-01-24

3. Stereodivergent Construction of 1,3‐Chiral Centers via Tandem Asymmetric Conjugate Addition and Allylic Substitution Reaction;Angewandte Chemie;2023-01-24

4. Structurally divergent enantioselective synthesis of benzofuran fused azocine derivatives and spiro-cyclopentanone benzofurans enabled by sequential catalysis;Chemical Science;2023

5. Stereodivergently asymmetric synthesis of chiral phosphorus compounds by synergistic combination of ion-pair catalyst and base;Science China Chemistry;2022-10-09