One-pot dual catalysis for the hydrogenation of heteroarenes and arenes

Author:

Chatterjee Basujit12345,Kalsi Deepti678,Kaithal Akash12345,Bordet Alexis678ORCID,Leitner Walter678910ORCID,Gunanathan Chidambaram12345ORCID

Affiliation:

1. School of Chemical Sciences

2. National Institute of Science Education and Research (NISER)

3. HBNI

4. Bhubaneswar-752050

5. India

6. Max Planck Institute for Chemical Energy Conversion

7. 45470 Mülheim an der Ruhr

8. Germany

9. Institut für Technische und Makromolekulare Chemie

10. RWTH Aachen University

Abstract

A catalytic system resulting from a monohydrido bridged ruthenium complex hydrogenated both heteroarenes and arenes, exhibited dual catalysis and provided access to valuable saturated heterocycles and cycloalkanes.

Funder

Science and Engineering Research Board

Deutsche Forschungsgemeinschaft

National Institute of Science Education and Research

Department of Atomic Energy, Government of India

Max-Planck-Gesellschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference70 articles.

1. F. Spindler and H.-U.Blaser , in Handbook of Homogeneous Hydrogenation , ed. J. G. D. Vries and C. J. Elsevier , Wiley-VCH , Weinheim , 2007 , p. 1193

2. The preparation and properties of tris(triphenylphosphine)halogenorhodium(I) and some reactions thereof including catalytic homogeneous hydrogenation of olefins and acetylenes and their derivatives

3. Homogeneous Hydrogenation and Hydroformylation using Ruthenium Complexes

4. R. H. Crabtree , The Organometallic Chemistry of the Transition Metals , John Wiley & Sons , New York , 2nd edn, 1994

5. Asymmetric hydrogenation of .beta.-keto carboxylic esters. A practical, purely chemical access to .beta.-hydroxy esters in high enantiomeric purity

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