A hydroboration route to geminal P/B frustrated Lewis pairs with a bulky secondary phosphane component and their reaction with carbon dioxide

Author:

Jian Zhongbao1234,Kehr Gerald1234ORCID,Daniliuc Constantin G.1234ORCID,Wibbeling Birgit1234,Erker Gerhard1234ORCID

Affiliation:

1. Organisch-Chemisches Institut

2. Universität Münster

3. 48149 Münster

4. Germany

Abstract

The hydroboration of a secondary alkynyl phosphane gives a geminal P/B frustrated Lewis pair that reacts with carbon dioxide.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference74 articles.

1. Frustrated Lewis Pair Chemistry I: Uncovering and Understanding, Top. Curr. Chem., ed. G. Erker and D. W. Stephan, Heidelberg, 2013, vol. 332

2. Frustrated Lewis Pair Chemistry II: Expanding the Scope, Top. Curr. Chem., ed. G. Erker and D. W. Stephan, Heidelberg, 2013, vol. 334

3. Frustrated Lewis Pair Chemistry: Development and Perspectives

4. The broadening reach of frustrated Lewis pair chemistry

5. Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane–borane adduct

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