Gas-phase spectroscopy of singly reduced tris(bipyridine)ruthenium ions, Ru(bipy)3+
Author:
Affiliation:
1. Department of Physics and Astronomy
2. Aarhus University
3. DK-8000 Aarhus C
4. Denmark
5. JILA and Department of Chemistry & Biochemistry
6. University of Colorado
7. Boulder
8. USA
Abstract
Light absorption in the visible region by isolated Ru(bipy)3+ (bipy = 2,2′-bipyridine) monocations, prepared in vacuo by reduction of dications in collisional electron transfer from cesium atoms, was recorded using photodissociation mass spectroscopy and found to be broad and similar to that of acetonitrile-solvated ions (maximum at 520 nm).
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CP/C4CP05477F
Reference28 articles.
1. Photochemistry and Photophysics of Coordination Compounds: Ruthenium
2. Ru(II) polypyridine complexes: photophysics, photochemistry, eletrochemistry, and chemiluminescence
3. Femtosecond Dynamics of Excited-State Evolution in [Ru(bpy) 3 ] 2+
4. Photophysics, photochemistry and solar energy conversion with tris(bipyridyl)ruthenium(II) and its analogues
5. Chemical approaches to artificial photosynthesis
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