X-ray crystallographic analysis of the antiferromagnetic low-temperature phase of galvinoxyl: investigating magnetic duality in organic radicals

Author:

Suizu Rie12ORCID,Shuku Yoshiaki1ORCID,Robert Vincent3ORCID,Roseiro Pablo3,Ben Amor Nadia4ORCID,Khawar Zain5,Robertson Neil5ORCID,Awaga Kunio1ORCID

Affiliation:

1. Department of Chemistry & Integrated Research Consortium on Chemical Sciences (IRCCS), Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan

2. Japan Science and Technology Agency (JST), PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan

3. Université de Strasbourg, CNRS, Laboratoire de Chimie Quantique UMR 7177, 67000 Strasbourg, France

4. Laboratoire de Physique et Chimie Quantiques, UMR 5626 Université Paul Sabatier, 118 route de Narbonne, 31062 Toulouse, France

5. School of Chemistry, The University of Edinburgh, Joseph Black Building, David Brewster Road, Edinburgh EH9 3FJ, UK

Abstract

Crystal structure of the low-temperature phase of galvinoxyl consists of a radical dimer with a significant overlap between the SOMOs.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Japan Society for the Promotion of Science

Japan Science and Technology Agency

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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