Synthesis, characterization and electronic properties of an endohedral plumbaspherene [Au@Pb12]3−-Reference-Cited by-同舟云学术

Synthesis, characterization and electronic properties of an endohedral plumbaspherene [Au@Pb12]3−

Published:2017 Issue:8 Volume:4 Page:1393-1396
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Li Lei-Jiao¹²³⁴⁵^ORCID,Pan Fu-Xing¹²³⁴⁵,Li Feng-Yu⁶⁷⁸⁹¹⁰,Chen Zhong-Fang⁶⁷⁸⁹¹⁰^ORCID,Sun Zhong-Ming¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Rare Earth Resource Utilization

2. Changchun Institute of Applied Chemistry

3. Chinese Academy of Sciences

4. Changchun

5. China

6. Department of Chemistry

7. Institute for Functional Nanomaterials

8. University of Puerto Rico

9. San Juan

10. USA

Abstract

A 12-vertex cluster [Au@Pb₁₂]³⁻ exhibits a distortion compared to I_h-[Pb₁₂]²⁻ cage. DFT calculations indicate that the NICS curves of [Pb₁₂]²⁻ and [Au@Pb₁₂]³⁻ share very similar character and tendency confirming their analogous aromaticity.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/QI/C7QI00209B

Reference36 articles.

1. Clusters, Superatoms, and Building Blocks of New Materials

2. Cluster-Assembled Materials

3. Magnetic properties of atomic clusters and endohedral metallofullerenes

4. Zintl Ions, Cage Compounds, and Intermetalloid Clusters of Group 14 and Group 15 Elements

5. From Clusters to Unorthodox Pnictogen Sources: Solution-Phase Reactivity of [E7]3–(E = P–Sb) Anions

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