Quantifying the barrier for the movement of cyclobis(paraquat-<i>p</i>-phenylene) over the dication of monopyrrolotetrathiafulvalene-Reference-Cited by-同舟云学术

Quantifying the barrier for the movement of cyclobis(paraquat-p-phenylene) over the dication of monopyrrolotetrathiafulvalene

Published:2022 Issue:11 Volume:20 Page:2233-2248
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Kristensen Rikke¹^ORCID,Neumann Mathias S.¹^ORCID,Andersen Sissel S.¹,Stein Paul C.¹,Flood Amar H.²^ORCID,Jeppesen Jan O.¹^ORCID

Affiliation:

1. Department of Physics, Chemistry and Pharmacy, University of Southern Denmark, Campusvej 55, DK-5230, Odense M, Denmark

2. Department of Chemistry, Indiana University, 800 E. Kirkwood Avenue, Bloomington, IN 47405-7102, USA

Abstract

Two positive charges generated by oxidation of a monopyrrolotetrathiafulvalene unit (green) raise an electrostatic barrier to decrease the speed of the deslipping of a tetracationic ring (blue) that take place in a [2]pseudorotaxane.

Funder

Villum Fonden

National Science Foundation

Det Frie Forskningsråd

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D1OB02263F

Reference64 articles.

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