Valence tautomerism in a cobalt-verdazyl coordination compound-Reference-Cited by-同舟云学术

Valence tautomerism in a cobalt-verdazyl coordination compound

Published:2020 Issue:32 Volume:56 Page:4400-4403
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Fleming Connor¹²³⁴⁵,Chung Dorothy¹²³⁴⁵,Ponce Servando¹²³⁴⁵,Brook David J. R.¹²³⁴⁵^ORCID,DaRos Jeffrey¹²³⁴⁵,Das Raja⁶⁷⁸⁵,Ozarowski Andrew⁹¹⁰¹¹⁵^ORCID,Stoian Sebastian A.¹¹²¹³⁵^ORCID

Affiliation:

1. Department of Chemistry

2. San Jose State University

3. One Washington Square

4. San Jose

5. USA

6. Department of Physics

7. University of South Florida

8. Tampa

9. National High Magnetic Field Laboratory

10. Florida State University

11. Tallahassee

12. University of Idaho

13. Moscow

Abstract

A cobalt bis(verdazyl) compound provides a new example of valence tautomerism in acetonitrile solution though the molecule is trapped in the ‘high energy’ tautomer in the crystalline material.

Funder

National Science Foundation

National Institutes of Health

University of Idaho

Lawrence Berkeley National Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC01770A

Reference27 articles.

1. Spin crossover in soft matter

2. Valence tautomerism in metal complexes: Stimulated and reversible intramolecular electron transfer between metal centers and organic ligands

3. Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

4. Rational design of potential spin qubits manipulated by the valence tautomerism mechanism: quantum-chemical modeling of the trinuclear transition metal complexes with bischelate linkers

5. Room Temperature Magnetic Switchability Assisted by Hysteretic Valence Tautomerism in a Layered Two-Dimensional Manganese-Radical Coordination Framework

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