Substitutional disorder: structure and ion dynamics of the argyrodites Li6PS5Cl, Li6PS5Br and Li6PS5I-Reference-Cited by-同舟云学术

Substitutional disorder: structure and ion dynamics of the argyrodites Li6PS5Cl, Li6PS5Br and Li6PS5I

Published:2019 Issue:16 Volume:21 Page:8489-8507
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Hanghofer I.¹²³⁴,Brinek M.¹²³⁴,Eisbacher S. L.¹²³⁴,Bitschnau B.⁵⁶³⁴,Volck M.⁷⁸⁴,Hennige V.⁷⁸⁴,Hanzu I.¹²³⁴⁹^ORCID,Rettenwander D.¹²³⁴^ORCID,Wilkening H. M. R.¹²³⁴⁹^ORCID

Affiliation:

1. Christian Doppler Laboratory for Lithium Batteries and Institute for Chemistry and Technology of Materials

2. Graz University of Technology (NAWI Graz)

3. 8010 Graz

4. Austria

5. Institute of Physical and Theoretical Chemistry

6. Graz University of Technology

7. AVL List GmbH

8. 8020 Graz

9. Alistore-ERI European Research Institute

Abstract

Li NMR spectroscopy reveals rapid Li ion dynamics in the poor Li ion conductor Li₆PS₅I; long-range motion is, however, only possible for Li₆PS₅Br and Li₆PS₅Cl with anion site disorder.

Funder

Christian Doppler Forschungsgesellschaft

Deutsche Forschungsgemeinschaft

Österreichische Forschungsförderungsgesellschaft

Bundesministerium für Wissenschaft, Forschung und Wirtschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP00664H

Reference84 articles.