Cationic tetranuclear macrocyclic CaCo<sub>3</sub> complexes as highly active catalysts for alternating copolymerization of propylene oxide and carbon dioxide-Reference-Cited by-同舟云学术

Cationic tetranuclear macrocyclic CaCo₃ complexes as highly active catalysts for alternating copolymerization of propylene oxide and carbon dioxide

Published:2023 Issue:31 Volume:14 Page:8262-8268
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Nagae Haruki¹^ORCID,Matsushiro Saki¹,Okuda Jun²^ORCID,Mashima Kazushi¹^ORCID

Affiliation:

1. Department of Chemistry, Graduate School of Engineering Science, Osaka University Toyonaka, Osaka 560-8531, Japan

2. Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, D-52062 Aachen, Germany

Abstract

We found that a cationic hetero tetranuclear complex including a calcium and three cobalts exhibited high catalytic activity toward alternating copolymerization of propylene oxide (PO) and carbon dioxide (CO2).

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC00974B

Reference87 articles.

1. Copolymerization of carbon dioxide and epoxide

2. D. J.Darensbourg , Salen metal complexes as catalysts for the synthesis of polycarbonates from cyclic ethers and carbon dioxide , in Synthetic Biodegradable Polymers , ed. B. Rieger , A. Künkel , G. W. Coates , R. Reichardt , E. Dinjus and T. A. Zevaco , Springer-Verlag , Berlin, Germany , 2012 , Advances in Polymer Science, 245 , pp. 1−27

3. G. A.Luinstra and E.Borchardt , Material properties of poly(propylene carbonates) , in Synthetic Biodegradable Polymers , ed. B. Rieger , A. Künkel , G. W. Coates , R. Reichardt , E. Dinjus and T. A. Zevaco , Springer-Verlag , Berlin, Germany , 2012 , Advances in Polymer Science, 245 , pp. 29−48

4. Multifunctional Catalysts for Ring-Opening Copolymerizations

5. Heterocycle/Heteroallene Ring‐Opening Copolymerization: Selective Catalysis Delivering Alternating Copolymers

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Synergic Catalysis: the Importance of Intermetallic Separation in Co(III)K(I) Catalysts for Ring Opening Copolymerizations;Journal of the American Chemical Society;2024-08-09

2. Quantifying CO₂ Insertion Equilibria for Low-Pressure Propene Oxide and Carbon Dioxide Ring Opening Copolymerization Catalysts;Journal of the American Chemical Society;2024-04-08

3. Bridging and terminal hydroxyl groups of Zr(OH)₄ as active sites for the ultraselective transformation of biomass-based alcohols;Catalysis Science & Technology;2024