Combined high degree of carboxylation and electronic conduction in graphene acid sets new limits for metal free catalysis in alcohol oxidation-Reference-Cited by-同舟云学术

Combined high degree of carboxylation and electronic conduction in graphene acid sets new limits for metal free catalysis in alcohol oxidation

Published:2019 Issue:41 Volume:10 Page:9438-9445
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Blanco Matías¹²³⁴⁵^ORCID,Mosconi Dario¹²³⁴⁵^ORCID,Otyepka Michal⁶⁷⁸⁹¹⁰^ORCID,Medveď Miroslav⁶⁷⁸⁹¹⁰,Bakandritsos Aristides⁶⁷⁸⁹¹⁰^ORCID,Agnoli Stefano¹²³⁴⁵^ORCID,Granozzi Gaetano¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemical Sciences

2. INSTM Unit

3. University of Padova

4. Padova

5. Italy

6. Regional Centre for Advanced Technologies and Materials

7. Faculty of Science

8. Palacký University Olomouc

9. 771 46 Olomouc

10. Czech Republic

Abstract

GO's weaknesses as metal-free catalyst are overcome by graphene acid (GA), who performs better than metals in alcohol oxidations. Mechanistic insights and DFT calculations unravel key aspects on the catalytic cycle for the control of the selectivity.

Funder

Ministero degli Affari Esteri e della Cooperazione Internazionale

H2020 European Research Council

Ministero dell’Istruzione, dell’Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC02954K

Reference38 articles.

1. Carbocatalysts: Graphene Oxide and Its Derivatives