Binuclear and tetranuclear Zn(ii) complexes with thiosemicarbazones: synthesis, X-ray crystal structures, ATP-sensing, DNA-binding, phosphatase activity and theoretical calculations-Reference-Cited by-同舟云学术

Binuclear and tetranuclear Zn(ii) complexes with thiosemicarbazones: synthesis, X-ray crystal structures, ATP-sensing, DNA-binding, phosphatase activity and theoretical calculations

Published:2020 Issue:22 Volume:10 Page:12735-12746
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Adak Piyali¹²³⁴,Ghosh Bipinbihari¹²³⁴,Bauzá Antonio¹⁵⁶⁷^ORCID,Frontera Antonio¹⁵⁶⁷^ORCID,Herron Steven R.¹⁸⁹¹⁰,Chattopadhyay Shyamal Kumar¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Engineering Science and Technology

3. Howarh-711 103

4. India

5. University of the Balearic Islands

6. 07122 Palma de Mallorca

7. Spain

8. Utah Valley University

9. Orem UT 84058

10. USA

Abstract

A binuclear and a tetranuclear zinc(ii) of pyruvaldehyde thiosemicarbazone show selective sensing of ATP at pH 7.4 (0.01 M HEPES) in CH₃CN–H₂O (9 : 1) medium. The DNA binding and phosphatase activities of the complexes are also reported.

Funder

University Grants Commission

Indian Institute of Engineering Science and Technology, Shibpur

Department of Science and Technology, Government of West Bengal

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/RA/C9RA10549B

Reference94 articles.

1. Fe(III) and Co(III) Centers with Carboxamido Nitrogen and Modified Sulfur Coordination: Lessons Learned from Nitrile Hydratase