Mono- and tri-ester hydrogenolysis using tandem catalysis. Scope and mechanism-Reference-Cited by-同舟云学术

Mono- and tri-ester hydrogenolysis using tandem catalysis. Scope and mechanism

Published:2016 Issue:2 Volume:9 Page:550-564
ISSN:1754-5692
Container-title:Energy & Environmental Science
language:en
Short-container-title:Energy Environ. Sci.

Author:

Lohr Tracy L.¹²³⁴,Li Zhi¹²³⁴,Assary Rajeev S.⁵⁶⁷⁴,Curtiss Larry A.⁵⁶⁷⁴⁸,Marks Tobin J.¹²³⁴

Affiliation:

1. Department of Chemistry

2. Northwestern University

3. Evanston

4. USA

5. Materials Science Division

6. Argonne National Laboratory

7. Argonne

8. Center for Nanoscale Materials

Abstract

The scope and mechanism of thermodynamically leveraged ester RC(O)O–R′ bond hydrogenolysis by tandem metal triflate + supported Pd catalysts are investigated both experimentally and theoretically by DFT and energy span analysis.

Funder

Office of Science

Division of Chemistry

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/EE/C5EE03256C

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