Photoelectrode/electrolyte interfacial band lineup engineering with alloyed III–V thin films grown on Si substrates

Author:

Piriyev Mekan1,Loget Gabriel2ORCID,Léger Yoan1ORCID,Le Hanh Vi3,Chen Lipin13,Létoublon Antoine1ORCID,Rohel Tony1,Levallois Christophe1ORCID,Le Pouliquen Julie1,Fabre Bruno2ORCID,Bertru Nicolas1ORCID,Cornet Charles1ORCID

Affiliation:

1. Univ Rennes, INSA Rennes, CNRS, Institut FOTON – UMR 6082, F-35000 Rennes, France

2. Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)–UMR6226, F-35000 Rennes, France

3. Tianjin Key Laboratory of Film, Electronic and Communication Devices, School of Integrated Circuit Science and Engineering, Tianjin University of Technology, Tianjin 300384, China

Abstract

In this work, we demonstrate how the classical concept of band gap engineering usually used in III–V semiconductor devices can be extended to the engineering of the band lineup between semiconducting photoelectrodes and electrolytes.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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