Coupling homogeneous and heterogeneous catalysis for enhancement of HCOOH electrooxidation via the dehydrogenation pathway

Author:

Li Yan1,Li Rui23,Liu Bin Hong4,Li Zhou Peng15ORCID

Affiliation:

1. College of Chemical & Biological Engineering, Zhejiang University, Hangzhou, China

2. Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, USA

3. Chu Kochen Honors College, Zhejiang University, Hangzhou, China

4. College of Materials Science & Engineering, Zhejiang University, Hangzhou, China

5. Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, Zhejiang University, Hangzhou, China

Abstract

The homogeneous/heterogeneous catalyst combination of VO2+/Pd protects Pd from CO-poisoning against HCOOH dehydration, controlling HCOOH electrooxidation processing via the dehydrogenation pathway, presenting commercially-favourable performance.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference21 articles.

1. In Direct Liquid Fuel Cells, Fundamentals, Advances and Future , ed. R. G. Akay and A. B. Yurtcan , 2020 , 1st edn, eBook ISBN: 9780128187364, Paperback ISBN: 9780128186244

2. Direct liquid fuel cells: A review

3. Direct formic acid fuel cells

4. Recent advances in formic acid electro-oxidation: from the fundamental mechanism to electrocatalysts

5. Recent advances in direct formic acid fuel cells (DFAFC)

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