Cerium photocatalyzed radical smiles rearrangement of 2-aryloxybenzoic acids
Author:
Affiliation:
1. School of Chemistry
2. Indian Institute of Science Education and Research
3. Thiruvananthapuram 695551
4. India
Abstract
Visible light-driven CeCl3-mediated aryl migration from an aryl ether to a carboxylic acid group through radical-Smiles rearrangement is reported.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/RA/D1RA04130D
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2. An Atom-Economic Synthesis of Bicyclo[3.1.0]hexanes by Rhodium N-Heterocyclic Carbene-Catalyzed Diastereoselective Tandem Hetero-[5 + 2] Cycloaddition/Claisen Rearrangement Reaction of Vinylic Oxiranes with Alkynes
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5. A truce on the Smiles rearrangement: revisiting an old reaction—the Truce–Smiles rearrangement
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