Interplay of structural dynamics and electronic effects in an engineered assembly of pentacene in a metal–organic framework

Author:

Haldar Ritesh1234ORCID,Kozlowska Mariana1534ORCID,Ganschow Michael6784,Ghosh Samrat910111213ORCID,Jakoby Marius11434,Chen Hongye123415,Ghalami Farhad161718194,Xie Weiwei161718194ORCID,Heidrich Shahriar1534,Tsutsui Yusuke910111213,Freudenberg Jan6784,Seki Shu910111213ORCID,Howard Ian A.114341ORCID,Richards Bryce S.114341ORCID,Bunz Uwe H. F.6784ORCID,Elstner Marcus161718194ORCID,Wenzel Wolfgang1534ORCID,Wöll Christof1234ORCID

Affiliation:

1. Karlsruhe Institute of Technology (KIT)

2. Institute of Functional Interfaces (IFG)

3. Eggenstein-Leopoldshafen

4. Germany

5. Institute of Nanotechnology (INT)

6. Organisch-Chemisches Institut

7. Ruprecht-Karls-Universität

8. 69120 Heidelberg

9. Department of Molecular Engineering

10. Graduate School of Engineering

11. Kyoto University

12. Kyoto 615-8510

13. Japan

14. Institute of Microstructure Technology (IMT)

15. State Key Laboratory of Mechanics and Control of Mechanical Structures

16. Karlsruhe Institute of Technology

17. Institute of Physical Chemistry (IPC)

18. Institute of Biological Interfaces (IBG2)

19. Karlsruhe

Abstract

Pentacene assembled into 1D arrays using a metal–organic framework (MOF) approach. This cofacial packing motif, which is not present in pentacene bulk, shows an interesting interplay of band-like and hopping-type transport.

Funder

Deutsche Forschungsgemeinschaft

Ministerium für Wissenschaft, Forschung und Kunst Baden-Württemberg

Japan Society for the Promotion of Science

Karlsruher Institut für Technologie

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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