Cyclometalated Pt(ii) complexes with a bidentate Schiff-base ligand displaying unexpected cis/trans isomerism: synthesis, structures and electronic properties
Author:
Affiliation:
1. Department of Chemistry
2. University of Milan
3. and SmartMatLab Center via Golgi 19
4. 20133 Milano
5. Italy
6. Institute of Molecular Science and Technology of the CNR (ISTM-CNR)
7. 20133 Milan
Abstract
Unexpected cis/trans isomerism in a bis-cyclometalated Pt(ii) complex is investigated by NMR, X-ray diffraction, optical, electrochemical and computational methods and rationalized.
Funder
Fondazione Cariplo
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02323E
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