The H-D-isotope effect of heavy water affecting ligand-mediated nanoparticle formation in SANS and NMR experiments-Reference-Cited by-同舟云学术

The H-D-isotope effect of heavy water affecting ligand-mediated nanoparticle formation in SANS and NMR experiments

Published:2023 Issue:40 Volume:15 Page:16413-16424
ISSN:2040-3364
Container-title:Nanoscale
language:en
Short-container-title:Nanoscale

Author:

Krauss Sebastian W.¹^ORCID,Eckardt Mirco¹,Will Johannes²^ORCID,Spiecker Erdmann²^ORCID,Siegel Renée³^ORCID,Dulle Martin⁴,Schweins Ralf⁵,Pauw Brian⁶,Senker Jürgen³^ORCID,Zobel Mirijam⁷^ORCID

Affiliation:

1. Department of Chemistry, University of Bayreuth, Universitätsstr. 30, 95447 Bayreuth, Germany

2. Institute of Micro- and Nanostructure Research & Center for Nanoanalysis and Electron Microscopy (CENEM), Friedrich-Alexander-Universität Erlangen-Nürnberg, IZNF, Cauerstraße 3, 91058 Erlangen, Germany

3. Inorganic Chemistry III and Northern Bavarian NMR Centre, University of Bayreuth, Universitätsstr. 30, 95447 Bayreuth, Germany

4. JCNS-1/IBI-8: Neutron Scattering and Biological Matter, Forschungszentrum Jülich Gmbh, Wilhelm-Johnen-Straße, 52428 Jülich, Germany

5. Institut Laue-Langevin, DS/LSS, 71 Avenue des Martyrs, Grenoble 38000, France

6. Bundesanstalt für Materialforschung und -prüfung (BAM), Unter den Eichen 87, 12205 Berlin, Germany

7. Institute of Crystallography, RWTH Aachen University, Jägerstr. 17-19, 52066 Aachen, Germany

Abstract

Changing from H2O to D2O in CdS nanoparticle formation creates an isotopic effect impacting particle formation. SANS and NMR reveal different complex building constants with the EDTA ligand and how these affect colloidal stability too.

Funder

Horizon 2020

Fonds der Chemischen Industrie

Elitenetzwerk Bayern

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2023/NR/D3NR02419A

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