Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 114. Ditungsten–digold compounds having two W(CC6H4Me-4)(CO)2(η5-C2B9H9Me2) fragments linked by AuP(Ph)2(CH2)n(Ph)2PAu (n= 2

Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 114. Ditungsten–digold compounds having two W(CC6H4Me-4)(CO)2(η5-C2B9H9Me2) fragments linked by AuP(Ph)2(CH2)n(Ph)2PAu (n= 2–6) groups

Published:1992 Issue:16 Volume: Page:2495-2502
ISSN:0300-9246
Container-title:J. Chem. Soc., Dalton Trans.
language:en
Short-container-title:J. Chem. Soc., Dalton Trans.

Author:

Goldberg Justin E.,Mullica Donald F.,Sappenfield Eric L.,Stone F. Gordon A.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/1992/DT/DT9920002495

Reference26 articles.

1. Synthesis and structural characterization of the compounds [WCoAu(.mu.3-CC6H4Me-4)(CO)2(PPh3)(.eta.5-C5Me5)(.eta.6-C2B10H10Me2)] and [MoCo(.mu.-CC6H4Me-4)(CO)2(.eta.4-C4Me4)(.eta.6-C2B10H10Me2)] and studies on related mixed-metal complexes

2. The Interplay of Alkylidyne and Carbaborane Ligands in the Synthesis of Electronically Unsaturated Mixed-Metal Complexes

3. Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 51. Alkylidyne(carbaborane)tungsten-gold and -rhodium complexes; crystal structures of [AuW(µ-CR)(CO)2(PPh3)(η-5C2B9H9Me2)], [RhW(µ-CR)(CO)2(PPh3)2(η5-C2B9H9Me2)], and (RhW[µ-CR)(CO)2(PPh3)2{η5-C2B9(C7H9)H8Me2}](R = C6H4Me-4)

4. Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 110. Synthesis of compounds with tungsten–copper or –gold bonds; crystal structure of [NEt4][W2Cu(µ-CCCBut)2(CO)4(η5-C2B9H9Me2)2]·Et2O

5. Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 98. Tri- and tetra-nuclear metal compounds with ethylidyne or p-tolylmethylidyne groups, and having both cyclopentadienyl and carbaborane ligands

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