Theoretical comparison of fructose with methylglucoside for the production of formate and levulinate catalyzed by Brønsted acids in a methanol solution-Reference-Cited by-同舟云学术

Theoretical comparison of fructose with methylglucoside for the production of formate and levulinate catalyzed by Brønsted acids in a methanol solution

Published:2024 Issue:23 Volume:26 Page:16664-16673
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Xiong Jin-Shan¹^ORCID,Min Han-Yun¹^ORCID,Qi Ting¹^ORCID,Zhang Yin-Sheng¹^ORCID,Hu Chang-Wei²^ORCID,Yang Hua-Qing¹^ORCID

Affiliation:

1. College of Chemical Engineering, Sichuan University, Chengdu, Sichuan, 610065, P. R. China

2. Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu, Sichuan, 610064, P. R. China

Abstract

The formate [HCOO]− comes from the dominant C1- and secondary C3-atoms of MG and from the C1-atom of fructose. Kinetically, MG is ready to yield (MF + MLev), whereas fructose can induce the reaction to remain at the HMF intermediate.

Funder

National Natural Science Foundation of China

Higher Education Discipline Innovation Project

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP01455C

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