Isolation and characterization of a lithiated pyridine – aggregation in the solid state and in solution

Author:

Schmidlin Nadja M. C.1234,Scherer Harald1234,Hoffmann Anke1234,Böttcher Tobias1234ORCID

Affiliation:

1. Institut für Anorganische und Analytische Chemie

2. Universität Freiburg

3. 79104 Freiburg

4. Germany

Abstract

The synthesis, isolation and characterization of the pyridyllithium compound 4-Li-2,6-Mes2py is reported. The crystal structure determination revealed a dimer in the solid state. In solution the pyridyllithium was identified as a monomer.

Funder

Deutsche Forschungsgemeinschaft

Verband der Chemischen Industrie

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference58 articles.

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4. M. Schlosser , Metalation of Azines and Diazines , Topics in Heterocyclic Chemistry , Springer , Berlin, Heidelberg , 2013 , vol. 31, pp. 171–222

5. R. G. Jones and H.Gilman , Organic Reactions , John Wiley and Sons, Inc. , 2011 , vol. 6, pp. 339–366

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4. Carbon‐metalated triazines and tetrazines: Synthesis and reactivity;Journal of Heterocyclic Chemistry;2020-07-29

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