Preparation of cycloheptane ring by nucleophilic cyclopropanation of 1,2-diketones with bis(iodozincio)methane-Reference-Cited by-同舟云学术

Preparation of cycloheptane ring by nucleophilic cyclopropanation of 1,2-diketones with bis(iodozincio)methane

Published:2015 Issue:1 Volume:13 Page:241-247
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Haraguchi Ryosuke¹²³⁴⁵,Takada Yoshiaki¹²³⁴⁵,Matsubara Seijiro¹²³⁴⁵

Affiliation:

1. Department of Material Chemistry

2. Graduate School of Engineering

3. Kyoto University

4. Kyoto 615-8510

5. Japan

Abstract

The nucleophlic cyclopropanation of hexa-1,5-diene-3,4-diones with bis(iodozincio)methane afforded the Zn alkoxides of cyclohepta-2,7-diene-1,2-diols stereospecifically via Zn alkoxides of cis-dialkenylcyclopropane-1,2-diols.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C4OB01474J

Reference30 articles.

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4. An Efficient [4 + 2 + 1] Entry to Seven-Membered Rings

5. Stereoselective Cyclopropanation Reactions

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