Boron-based inorganic heterocyclic clusters: electronic structure, chemical bonding, aromaticity, and analogy to hydrocarbons-Reference-Cited by-同舟云学术

Boron-based inorganic heterocyclic clusters: electronic structure, chemical bonding, aromaticity, and analogy to hydrocarbons

Published:2019 Issue:37 Volume:21 Page:20523-20537
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Feng Lin-Yan¹²³⁴⁵,Li Rui¹²³⁴⁵,Zhai Hua-Jin¹²³⁴⁵^ORCID

Affiliation:

1. Nanocluster Laboratory

2. Institute of Molecular Science

3. Shanxi University

4. Taiyuan 030006

5. China

Abstract

Boron-based heterocyclic clusters feature rhombic/pentagonal o-bonds, inorganic benzenes, and chemical analogy to hydrocarbons and PAHs. One electron overturns the potential landscape in certain cases.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP03254A

Reference82 articles.

1. The Boranes and Their Relatives

2. Boron Cluster Cations: Transition from Planar to Cylindrical Structures

3. SystematicLSD investigation on cationic boron clusters: Bn+(n ? 2-14)

4. The Curiously Stable Cluster and its Neutral and Anionic Counterparts: The Advantages of Planarity

5. B13+ Is Highly Aromatic

Cited by 18 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Is There an Adduct of Pyridine N-Oxide and Boron Trifluoride in the Gaseous State? Gas Electron Diffraction vs Mass Spectrometry;Inorganic Chemistry;2024-08-19

2. Three-fold π delocalisation bonding pattern in bowl-like B ₇₀ cluster: an all-boron analogue of the nanographene molecule C ₄₈ H ₁₈;Molecular Physics;2024-08-02

3. Heterocyclic hexagonal B5O7− and B5O8− clusters: Inorganic benzenes and phenolate anions, dual 3c-4e hypervalent π bonds, and superhalogen anions;Journal of Molecular Structure;2024-01

4. Boron Oxide B5O6− Cluster as a Boronyl-Based Inorganic Analog of Phenolate Anion;Frontiers in Chemistry;2022-04-08

5. Structures and chemical bonding of boron-based B₁₂O and B₁₁Au clusters. A counterexample in boronyl chemistry;Physical Chemistry Chemical Physics;2022