Highly soluble C2v-symmetrical fullerene derivatives: efficient synthesis, characterization, and electrochemical study-Reference-Cited by-同舟云学术

Highly soluble C2v-symmetrical fullerene derivatives: efficient synthesis, characterization, and electrochemical study

Published:2019 Issue:9 Volume:6 Page:1372-1377
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Ma Yue¹²³⁴⁵,Uchiyama Kouya⁶⁷⁸⁹¹⁰,Ueno Hiroshi⁵¹¹¹²⁴^ORCID,Okada Hiroshi¹³¹⁴¹⁵¹⁶¹⁰^ORCID,Moriyama Hiroshi⁶⁷⁸⁹¹⁰,Matsuo Yutaka¹²³⁴¹³^ORCID

Affiliation:

1. Hefei National Laboratory for Physical Science at the Microscale

2. University of Science and Technology of China

3. Hefei

4. China

5. School of Chemistry

6. Department of Chemistry

7. Faculty of Science

8. Toho University

9. Funabashi

10. Japan

11. Northeast Normal University

12. Changchun

13. Department of Mechanical Engineering

14. School of Engineering

15. The University of Tokyo

16. Tokyo 113-8656

Abstract

Through an efficient octa-substitution reaction, octabromofullerene (C₆₀Br₈) was reacted with alcohols or anisole in the presence of silver triflate to produce octaalkoxy and octaaryl fullerenes, respectively, in up to 79% yield with retention of C_2v-symmetry.

Funder

Northeast Normal University

Ministry of Knowledge Economy

Ministry of Education, Culture, Sports, Science and Technology

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QO/C9QO00056A

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