C–H bond activation at antimony(<scp>iii</scp>): synthesis and reactivity of Sb(<scp>iii</scp>)

C–H bond activation at antimony(iii): synthesis and reactivity of Sb(iii)–oxyaryl species

Published:2024 Issue: Volume: Page:
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Duneş Gabriel¹²,Cordier Marie¹,Kahlal Samia¹,Pöllnitz Alpar²,Saillard Jean-Yves¹,Silvestru Cristian²^ORCID,Sarazin Yann¹^ORCID

Affiliation:

1. Université de Rennes, CNRS, Institut des Sciences Chimiques de Rennes, UMR 6226, Campus de Beaulieu, 35042 Rennes, Cedex, France

2. Department of Chemistry, Supramolecular Organic and Organometallic Chemistry Centre (SOOMCC), Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, 11 Arany Janos, 400028 Cluj-Napoca, Romania

Abstract

The antimony(iii)-oxyaryl [{NCNMe4}Sb(C6H2-tBu2-3,5-O-4)] forms upon C–H activation, with charged species and heterolytic bond cleaving and forming steps. The reactivity of the complex, which exhibits zwitterionic and quinoidal features, was probed.

Funder

Agence Nationale de la Recherche

Unitatea Executiva pentru Finantarea Invatamantului Superior, a Cercetarii, Dezvoltarii si Inovarii

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01400F

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