Synthesis and reactivity of N-heterocyclic carbene (NHC) gold-fluoroalkoxide complexes-Reference-Cited by-同舟云学术

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Synthesis and reactivity of N-heterocyclic carbene (NHC) gold-fluoroalkoxide complexes

Published:2024 Issue:28 Volume:53 Page:11952-11958
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Arnaut Pierre¹,Bracho Pozsoni Nestor¹,Nahra Fady¹²^ORCID,Tzouras Nikolaos V.¹^ORCID,Nolan Steven P.¹^ORCID

Affiliation:

1. Department of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281, S-3, 9000 Ghent, Belgium

2. Materials & Chemistry (MATCH) unit, VITO (Flemish Institute for Technological Research), Boeretang 200, 2400 Mol, Belgium

Abstract

We report a new family of gold-fluoroalkoxide complexes bearing various NHC ligands, and gauge their potential in organometallic synthesis.

Funder

Fonds Wetenschappelijk Onderzoek

Universiteit Gent

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01402B

Reference43 articles.

1. Fluorinated Alcohols: Magic Reaction Medium and Promoters for Organic Synthesis

2. Fluorinated Alcohols As Promoters for the Metal-Free Direct Substitution Reaction of Allylic Alcohols with Nitrogenated, Silylated, and Carbon Nucleophiles

3. Studies on the Origin of the Stabilizing Effects of Fluorinated Alcohols and Weakly Coordinated Fluorine-Containing Anions on Cationic Reaction Intermediates

4. Hydrogen Bonding Cluster-Enabled Addition of Sulfonic Acids to Haloalkynes: Access to Both (E)- and (Z)-Alkenyl Sulfonates

5. Fluorinated alcohols: A magic medium for the synthesis of heterocyclic compounds

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