Two types of Ln2Cu2 hydroxo-trimethylacetate complexes with 0D and 1D motifs: synthetic features, structural differences, and slow magnetic relaxation-Reference-Cited by-同舟云学术

Two types of Ln2Cu2 hydroxo-trimethylacetate complexes with 0D and 1D motifs: synthetic features, structural differences, and slow magnetic relaxation

Published:2021 Issue:35 Volume:50 Page:12275-12286
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bovkunova Anna A.¹^ORCID,Bazhina Evgeniya S.¹^ORCID,Evstifeev Igor S.¹^ORCID,Nelyubina Yulia V.²,Shmelev Maxim A.¹^ORCID,Babeshkin Konstantin A.¹^ORCID,Efimov Nikolay N.¹,Kiskin Mikhail A.¹^ORCID,Eremenko Igor L.¹²^ORCID

Affiliation:

1. N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninsky prosp. 31, Moscow 119991, Russia

2. A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova st. 28, Moscow 119991, Russia

Abstract

The insertion of Na+ ions into the structure of LnIII2CuII2 hydroxo-trimethylacetate complexes leads to a change in the butterfly-like metal core geometry giving rise to a significant change in their slow magnetic relaxation.

Funder

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT01161H

Reference68 articles.

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3. Spin dynamics in single-molecule magnets and molecular qubits