Cleavage of an aryl carbon–nitrogen bond of a phosphazido iron(ii) complex promoted by hydride metathesis
Author:
Affiliation:
1. Nagoya Institute of Technology
2. Nagoya 466-8555
3. Japan
4. Department of Chemistry
5. University of British Columbia
6. Vancouver
7. Canada
Abstract
The unexpected reaction of a Fe(ii) enamidophosphazide complex with KBEt3H, which results in the elimination of N2 and 1,3-Me2C6H4 to generate a dinuclear Fe(ii) derivative with bridging phosphinimido units, is presented along with mechanistic studies.
Funder
Japan Society for the Promotion of Science
Natural Sciences and Engineering Research Council of Canada
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03136A
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