Actinide-transition metal bonding in heterobimetallic uranium– and thorium–molybdenum paddlewheel complexes

Author:

Ayres Alexander J.1234,Zegke Markus51674,Ostrowski Joseph P. A.51674,Tuna Floriana8674ORCID,McInnes Eric J. L.8674,Wooles Ashley J.51674,Liddle Stephen T.51674ORCID

Affiliation:

1. School of Chemistry

2. The University of Nottingham

3. Nottingham

4. UK

5. Centre for Radiochemistry Research

6. The University of Manchester

7. Manchester

8. School of Chemistry and Photon Science Institute

Abstract

Heterobimetallic An–Mo (An = U, Th) paddlewheel complexes featuring dative Mo → An bonds are reported.

Funder

Engineering and Physical Sciences Research Council

Royal Society

European Research Council

University of Manchester

University of Nottingham

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference79 articles.

1. Multiple Bonds Between Metal Atoms , ed. F. A. Cotton , C. A. Murillo and R. A. Walton , Springer-Verlag , New York , 3rd edn, 2005

2. Molecular Metal–Metal Bonds: Compounds, Synthesis, Properties , ed. S. T. Liddle , Wiley VCH , Weinheim, Germany , 2015

3. Rare earth–metal bonding in molecular compounds: recent advances, challenges, and perspectives

4. f-Element-metal bond chemistry

5. f-Element-Metal Bonding and the Use of the Bond Polarity To Build Molecular Intermetalloids

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