Connecting supramolecular bond lifetime and network mobility for scratch healing in poly(butyl acrylate) ionomers containing sodium, zinc and cobalt-Reference-Cited by-同舟云学术

Connecting supramolecular bond lifetime and network mobility for scratch healing in poly(butyl acrylate) ionomers containing sodium, zinc and cobalt

Published:2015 Issue:3 Volume:17 Page:1697-1704
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Bose Ranjita K.¹²³⁴⁵,Hohlbein Nico⁶⁷⁸⁹,Garcia Santiago J.¹²³⁴⁵,Schmidt Annette M.⁶⁷⁸⁹,van der Zwaag Sybrand¹²³⁴⁵

Affiliation:

1. Novel Aerospace Materials

2. Faculty of Aerospace Engineering

3. Delft University of Technology

4. Delft 2629HS

5. The Netherlands

6. Chemistry Department

7. University of Cologne

8. D-50939 Cologne

9. Germany

Abstract

We correlate network dynamics, supramolecular reversibility and the macroscopic surface scratch healing behavior for a series of ionomers based on an amorphous backbone with varying fractions of carboxylate pendant groups completely neutralized by Na⁺, Zn²⁺, or Co²⁺ as the counter ions.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C4CP04015E

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