The influence of depropagation on PEGMA9 solution radical homopolymerization and copolymerization with DEAEMA: in situ1H-NMR measurements and reactivity ratio estimation by dynamic optimization-Reference-Cited by-同舟云学术

The influence of depropagation on PEGMA₉ solution radical homopolymerization and copolymerization with DEAEMA: in situ¹H-NMR measurements and reactivity ratio estimation by dynamic optimization

Published:2024 Issue:3 Volume:15 Page:143-155
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Cabello-Romero Judith¹,Torres-Lubián Román¹,Enríquez-Medrano Francisco Javier¹,Hutchinson Robin A.²,Zapata-González Iván³^ORCID

Affiliation:

1. Dpto. de Química Macromolecular y Nanomateriales, Centro de Investigación en Química Aplicada (CIQA), #140, Blvd. Enrique Reyna Hermosillo, Saltillo, 25294, Coahuila, Mexico

2. Department of Chemical Engineering, Dupuis Hall, Queen's University, Kingston, Ontario K7L 3N6, Canada

3. Dpto. de Procesos de Polimerización, Centro de Investigación en Química Aplicada (CIQA), #140, Blvd. Enrique Reyna Hermosillo, Saltillo, 25294, Coahuila, Mexico

Abstract

The concentration affects the depropagation–propagation equilibrium of PEGMA9 due to the backbone flexibility, but this effect on its copolymerization with DEAEMA is negligible.

Funder

Consejo Estatal de Ciencia y Tecnología del Estado de Coahuila

Centro de Investigación en Química Aplicada

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2024/PY/D3PY01087B

Reference44 articles.

1. Polymerization of oligo(ethylene glycol) (meth)acrylates: Toward new generations of smart biocompatible materials

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