Mechanistic insights into the incorporation of higher alpha-olefins into acrylate copolymers <i>via</i> photoATRP-Reference-Cited by-同舟云学术

Mechanistic insights into the incorporation of higher alpha-olefins into acrylate copolymers via photoATRP

Published:2024 Issue:5 Volume:15 Page:438-453
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Sharma Bhawna¹²,Verma Akash¹²,Tak Anuj³,Saini Swati¹²,Bhati Kapil¹,Rajagopala Rao Tammineni³^ORCID,Kumar Umesh¹²^ORCID

Affiliation:

1. Polymeric Materials Area, Chemical and Material Sciences Division, CSIR - Indian Institute of Petroleum, Haridwar Road, Dehradun – 248005, India

2. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad – 201002, India

3. Department of Chemistry, Indian Institute of Technology Patna, Bihta, Bihar – 801106, India

Abstract

Visible light-driven SR & NI photoATRP with CuIIBr2/L yielded acrylate-α-olefin copolymers (Đ ≤ 1.13) incorporating up to 30% α-olefins. DFT revealed low activation energy barriers (14.3 kcal mol−1 and 17.8 kcal mol−1) for PCA2 and PCB2 formation.

Funder

Department of Science & Technology, Ministry of Science and Technology, India

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2024/PY/D3PY01080E

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5. Copper-Mediated Controlled Copolymerization of Methyl Acrylate with 1-Alkenes under Mild Conditions