Copper(i)/succinic acid cooperatively catalyzed one-pot synthesis of organoselenium-propargylamines via A3-coupling-Reference-Cited by-同舟云学术

Copper(i)/succinic acid cooperatively catalyzed one-pot synthesis of organoselenium-propargylamines via A3-coupling

Published:2018 Issue:12 Volume:42 Page:10118-10123
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

de Oliveira Isadora M.¹²³⁴⁵^ORCID,Pimenta Daniel C.⁶⁷⁴⁵^ORCID,Zukerman-Schpector Julio⁸⁹¹⁰⁵,Stefani Hélio A.¹¹¹²³⁴⁵^ORCID,Manarin Flávia¹³¹⁴¹⁵⁵

Affiliation:

1. Departamento de Química Fundamental

2. Instituto de Química

3. Universidade de São Paulo

4. São Paulo

5. Brazil

6. Laboratório de Bioquímica e Biofísica

7. Instituto Butantan

8. Departamento de Química

9. Universidade Federal de São Carlos

10. São Carlos

11. Departamento de Farmácia

12. Faculdade de Ciências Farmacêuticas

13. Centro de Engenharias e Ciências Exatas- CECE

14. Universidade Estadual do Oeste do Paraná

15. Toledo

Abstract

Selenium propargylamines were synthesized via an A³-coupling approach using piperidine, p-methoxybenzaldehyde, and trimethylsilyl selenium–acetylene, catalyzed by copper(i) chloride and succinic acid as an additive, in good to excellent yields.

Funder

Fundação de Amparo à Pesquisa do Estado de São Paulo

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Financiadora de Estudos e Projetos

Fundação Araucária

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C8NJ01543K

Reference43 articles.

1. Synthesis and Reactivity of Propargylamines in Organic Chemistry

2. Indium-Catalyzed Highly Efficient Three-Component Coupling of Aldehyde, Alkyne, and Amine via C−H Bond Activation

3. The solid phase synthesis of complex propargylamines using the combination of sonogashira and mannich reactions

4. Highly efficient Grignard-type imine additions via C–H activation in water and under solvent-free conditions

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