Long-lived MLCT states for Ru(ii) complexes of ferrocene-appended 2,2′-bipyridines

Author:

Barnsley Jonathan E.12345ORCID,Findlay James A.12345ORCID,Shillito Georgina E.12345ORCID,Pelet William S.12345,Scottwell Synøve Ø.12345,McIntyre Sam M.12345,Tay Elliot J.12345,Gordon Keith C.12345ORCID,Crowley James D.12345ORCID

Affiliation:

1. Department of Chemistry

2. University of Otago

3. Dunedin

4. New Zealand

5. MacDiarmid Institute for Advanced Materials and Nanotechnology

Abstract

In this study, we present two ruthenium(ii) diimine complexes appended with ferrocene which show metal to ligand charge transfer 3MLCT emission lifetimes around 630 ns.

Funder

University of Otago

Marsden Fund

MacDiarmid Institute for Advanced Materials and Nanotechnology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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