The synthesis and magnetic properties of a linear mixed-valence [Ni3]5+ in an anthyridine tri-nickel complex-Reference-Cited by-同舟云学术

The synthesis and magnetic properties of a linear mixed-valence [Ni3]5+ in an anthyridine tri-nickel complex

Published:2019 Issue:27 Volume:48 Page:9912-9915
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Hsieh Chang-Lin¹²³⁴^ORCID,Liu Tsai-Jung¹²³⁴^ORCID,Song You⁵⁶⁷⁸⁹^ORCID,Lee Gene-Hsiang¹²³⁴,Jin Bih-Yaw¹²³⁴,Lin Tien-Sung¹²³⁴,Peng Shie-Ming¹²³⁴¹⁰

Affiliation:

1. Department of Chemistry

2. National Taiwan University

3. Taipei

4. Republic of China

5. State Key Laboratory of Coordinate Chemistry

6. School of Chemistry and Chemical Engineering

7. Nanjing National Laboratory of Microstructures

8. Nanjing University

9. P. R. China

10. Institute of Chemistry

Abstract

A novel trinuclear complex [Ni₃(μ₃-dbay)₄Cl₂]I₃ (1) with a mixed-valence state was prepared by reacting the tridentate ligand 1,13,14-triaza-dibenz[a,j]anthracene (dibenzanthyridine = dbay) with anhydrous NiCl₂ and sodium tetraphenylborate.

Funder

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02022E

Reference15 articles.

1. Weak antiferromagnetic coupling for novel linear hexanuclear nickel(ii) string complexes (Ni612+) and partial metal–metal bonds in their one-electron reduction products (Ni611+)

2. A New Generation of Metal String Complexes: Structure, Magnetism, Spectroscopy, Theoretical Analysis, and Single Molecular Conductance of an Unusual Mixed-Valence Linear [Ni5]8+ Complex

3. Binuclear complex of 1.5 valent nickel

4. Synthesis and characterization of 1,8-naphthyridine complexes of 1.5-valent nickel

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