Slow relaxation of the magnetization observed in mononuclear Ln–radical compounds with D4d geometry configurations

Author:

Chen Peng Yun12345,Wu Ming Ze12345,Liu Zhong Yi12345,Tian Li12345ORCID,Zhang Yi Quan678910ORCID

Affiliation:

1. College of Chemistry

2. Tianjin Key Laboratory of Structure and Performance for Functional Molecules

3. Key Laboratory of Inorganic-Organic Hybrid Functional Materials Chemistry

4. Ministry of Education

5. Tianjin Normal University

6. Sch Phys Sci & Technol

7. Jiangsu Key Lab NSLSCS

8. Nanjing Normal Univ

9. Nanjing 210023

10. P. R. China

Abstract

Three monometallic Ln-NIT complexes have been synthesized based on a pyrazole radical. The central LnIII ions are all in D4d polyhedron configurations. Tb's complex shows a single relaxation process. Dy's complex exhibits complicated relaxation processes.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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