Sequential enhancement of proton conductivity by aliovalent cadmium substitution and post-synthetic esterolysis in a carboxylate-functionalized indium framework with dimethylaminium templates-Reference-Cited by-同舟云学术

Sequential enhancement of proton conductivity by aliovalent cadmium substitution and post-synthetic esterolysis in a carboxylate-functionalized indium framework with dimethylaminium templates

Published:2022 Issue:12 Volume:9 Page:2997-3002
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Gao Hui¹²^ORCID,Wang Ying-Xia¹^ORCID,He Yan-Bin²^ORCID,Zhang Xian-Ming¹³^ORCID

Affiliation:

1. Key Laboratory of Magnetic Molecules and Magnetic Information Material of Ministry of Education, School of Chemistry and Material Science, Shanxi Normal University, Taiyuan, Shanxi, 030006, P. R China

2. Department of Pharmacy, Changzhi Medical College, Changzhi, Shanxi, 046000, P. R. China

3. College of Chemistry & Chemical Engineering, Key Laboratory of Interface Science and Engineering in Advanced Material, Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, P. R. China

Abstract

A sequential improving strategy of aliovalent Cd(ii) substitution and post-synthetic ligand esterolysis has been proposed and implemented on a In(iii)-MOF. The modified framework Cd-BQ-COOH exhibits 300-fold enhanced value of proton conductivitiy.

Funder

National Natural Science Foundation of China

Shanxi Province Science Foundation for Youths

Shanxi Scholarship Council of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QI/D2QI00407K

Reference43 articles.

1. Transport in Proton Conductors for Fuel-Cell Applications: Simulations, Elementary Reactions, and Phenomenology