Trifunctionalization of CC bonds in vinyl azides to access densely functionalized phenanthridines enabled by the NCS/AgNO2 system

Author:

Ren Shaobo12,Zhu Jian2,Liu Yunkui2ORCID

Affiliation:

1. College of Pharmacy, Jinhua Polytechnic, Jinhua, 321007, P. R. China

2. State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310014, P. R. China

Abstract

The NCS/AgNO2 system enables an unprecedented trifunctionalization of CC bonds in vinyl azides to access densely functionalized phenanthridines in a one-pot manner.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Zhejiang Province

Jinhua Science and Technology Bureau

Publisher

Royal Society of Chemistry (RSC)

Reference74 articles.

1. N.Ono , The Nitro Group in Organic Synthesis , Wiley-VCH , New York , 2001

2. H.Feuer and A. T.Nielson , Nitro Compounds: Recent Advances in Synthesis and Chemistry , VCH , Weinheim , 1990

3. Nitroalkanes as Key Compounds for the Synthesis of Amino Derivatives

4. Conjugated nitroalkenes: versatile intermediates in organic synthesis

5. R.Ballini , E.Marcantoni and M.Petrini , in Amino Group Chemistry , ed. E. Ricci , Wiley-VCH , Weinheim , 2008 , pp 93–148

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