Synthesis of hydroxylated azacalix[1]arene[3]pyridines from hydrolysis of high valent arylcopper complexes and conversion to a double azacalix[1]arene[3]pyridine host molecule-Reference-Cited by-同舟云学术

Synthesis of hydroxylated azacalix[1]arene[3]pyridines from hydrolysis of high valent arylcopper complexes and conversion to a double azacalix[1]arene[3]pyridine host molecule

Published:2017 Issue:2 Volume:4 Page:283-287
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zhang Qian¹²³⁴⁵^ORCID,Wang Mei-Xiang¹²³⁴⁵

Affiliation:

1. Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education)

2. Department of Chemistry

3. Tsinghua University

4. Beijing 100084

5. China

Abstract

Arylcopper(ii) compounds reacted efficiently with KOH at ambient temperature to produce exclusively lower-rim-hydroxylated azacalix[1]arene[3]pyridines which underwent further CuCl₂/TMEDA-catalyzed oxidative homocoupling to afford an unprecedented bisazacalix[1]phenol[3]pyridine host molecule.

Funder

Tsinghua University

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/QO/C6QO00669H

Reference49 articles.

1. Heterocalixaromatics, new generation macrocyclic host molecules in supramolecular chemistry

2. Nitrogen and Oxygen Bridged Calixaromatics: Synthesis, Structure, Functionalization, and Molecular Recognition